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The entropy of vaporization is the increase in entropy upon vaporization of a liquid. This is always positive since the degree of disorder increases in the transition from a liquid in a relatively small volume to a vapor or gas occupying a much larger space. At standard pressure P In a phase transition such as vaporization, both phases coexist in equilibrium, so the difference in Gibbs free energy is equal to zero. :, where is the heat or enthalpy of vaporization. Since this is a thermodynamic equation, the symbol T refers to the absolute thermodynamic temperature, measured in Kelvin (K). The entropy of vaporization is then equal to the heat of vaporization divided by the boiling point. : According to Trouton's rule, the entropy of vaporization (at standard pressure) of most liquids is about 85 to 88 J mol−1 K−1. ==See also== *Entropy of fusion 抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「Entropy of vaporization」の詳細全文を読む スポンサード リンク
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